Table 3. Parameterization of entropy... | Rockefeller University Press

Table 3.

Parameterization of entropy change

Titrant (syringe)	Titrand (cell)		ΔC_p (J/mol·K)	−ΔS_Sum at °25 C (J/mol·K)	−ΔS_Mix (J/mol·K)	−ΔS_Solv (J/mol·K)	−ΔS_Conf (J/mol·K)
Mel	MelB_St	/	643.01	28.41	33.00	164.61	−169.20
Na⁺	MelB_St	/	1305.20	12.24	33.00	334.13	−354.89
Mel	MelB_St	Na⁺	−424.93	−15.92	33.00	−108.78	59.86
Na⁺	MelB_St	Mel	−760.50	−12.82	33.00	−194.56	148.74

Titrant (syringe)	Titrand (cell)		ΔC_p (J/mol·K)	−ΔS_Sum at °25 C (J/mol·K)	−ΔS_Mix (J/mol·K)	−ΔS_Solv (J/mol·K)	−ΔS_Conf (J/mol·K)
Mel	MelB_St	/	643.01	28.41	33.00	164.61	−169.20
Na⁺	MelB_St	/	1305.20	12.24	33.00	334.13	−354.89
Mel	MelB_St	Na⁺	−424.93	−15.92	33.00	−108.78	59.86
Na⁺	MelB_St	Mel	−760.50	−12.82	33.00	−194.56	148.74

Calculation of each parameter is described in Materials and methods. −ΔS_Sum = −TΔS/298.15 as measured at 25°C in Table 2.