Table 1.

Gibbs free energies and equilibrium dissociation constants for single- and double-ion occupancy from 2-D PMF computations

Occupancy group Occupancy Dissociation constant (mol/L) ΔG (kcal/mol) 
  KD(single) KD(double) ΔG 
Single-ion occupancy Na 4.88E-14  −19.19 
 7.56E-12  −16.03 
Na at innermost position Na–Na  4.27E-03 −3.42 
 K–Na  8.44E-03 −2.99 
K at innermost position K–K  9.85E-03 −2.89 
 Na–K  7.29E-03 −3.08 
Occupancy group Occupancy Dissociation constant (mol/L) ΔG (kcal/mol) 
  KD(single) KD(double) ΔG 
Single-ion occupancy Na 4.88E-14  −19.19 
 7.56E-12  −16.03 
Na at innermost position Na–Na  4.27E-03 −3.42 
 K–Na  8.44E-03 −2.99 
K at innermost position K–K  9.85E-03 −2.89 
 Na–K  7.29E-03 −3.08 

Values were calculated from the following data: KD (single) for Na, from Fig. 3 A, and from equivalent data for K; KD (double) from the data in the 2-D PMFs in Fig. 3 C.

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