TABLE VI. Rate constants and partial... | Rockefeller University Press

TABLE VI.

Rate constants and partial charges for scheme I at 30°C

Transition	K₀^a	q_eff^b
	s⁻¹	e_o
O1-C3	2,594 ± 399	0.032 ± 0.110
C3-O1	3,519 ± 638	−0.023 ± 0.042
O2-C4	10,239 ± 1,202	−0.064 ± 0.050
C4-O2	775 ± 171	0.231 ± 0.173
C3-C4	596 ± 86	0.291 ± 0.121*
C4-C3	16.9 ± 6.1	0.903 ± 0.265*
C4-C5	866 ± 187	0.099 ± 0.156
C5-C4	74.8 ± 28.8	0.398 ± 0.159
C5-C6	70.6 ± 27.9	0.206 ± 0.235
C6-C5	12.1 ± 3.2	0.410 ± 0.218
C6-C7	0.94 ± 0.43	0.344 ± 0.218
C7-C6	5.13 ± 3.27	0.223 ± 0.213

Transition	K₀^a	q_eff^b
	s⁻¹	e_o
O1-C3	2,594 ± 399	0.032 ± 0.110
C3-O1	3,519 ± 638	−0.023 ± 0.042
O2-C4	10,239 ± 1,202	−0.064 ± 0.050
C4-O2	775 ± 171	0.231 ± 0.173
C3-C4	596 ± 86	0.291 ± 0.121*
C4-C3	16.9 ± 6.1	0.903 ± 0.265*
C4-C5	866 ± 187	0.099 ± 0.156
C5-C4	74.8 ± 28.8	0.398 ± 0.159
C5-C6	70.6 ± 27.9	0.206 ± 0.235
C6-C5	12.1 ± 3.2	0.410 ± 0.218
C6-C7	0.94 ± 0.43	0.344 ± 0.218
C7-C6	5.13 ± 3.27	0.223 ± 0.213

Rate constants at 0 mV were estimated from individually fitted rate constants at 40 and 100 mV from 9 and 13 different channels (30°C), respectively (see Materials and methods). The SEM values were estimated from the SEM of the individual experiments.

Effective partial charges for the indicated rate constants were obtained from simultaneous fitting of scheme I to eight different channels (30°C) at 40 and 100 mV. The significance was estimated using a Wilcoxon signed ranks test (*, P < 0.05).

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