Parameters of the kinetic model
| Rate constant | k0 ILT | zk ILT | k0(a) | zka |
| ms−1 | e0 | ms−1 | e0 | |
| α00 | 17.3 | 0.20 | 0.3659 | 0.3965 |
| β00 | 0.00006 | 3.4 | 0.0001 | 2.5084 |
| α10 | 0.17 | 0.04 | 2.9902 | 0.0037 |
| β10 | 0.00003 | 0.97 | 0.4255 | 1.1015 |
| α20 | 1.19 | 1.02 | 0.2586 | 0.0001 |
| β20 | 1.43 | 0.000004 | 2.4364 | 0.0261 |
| Rate constant | k0 ILT | zk ILT | k0(a) | zka |
| ms−1 | e0 | ms−1 | e0 | |
| α00 | 17.3 | 0.20 | 0.3659 | 0.3965 |
| β00 | 0.00006 | 3.4 | 0.0001 | 2.5084 |
| α10 | 0.17 | 0.04 | 2.9902 | 0.0037 |
| β10 | 0.00003 | 0.97 | 0.4255 | 1.1015 |
| α20 | 1.19 | 1.02 | 0.2586 | 0.0001 |
| β20 | 1.43 | 0.000004 | 2.4364 | 0.0261 |
The rate constants are given for the model presented in Scheme 1. Forward and backward rate constants are α and b, respectively, and follow exponential voltage dependence as α0 = α00*e(z0f*Vm*F/RT) and β0 = β00*e(-z0b*Vm*F/RT). The k0 column gives each of the rates at 0 mV, and the zk column indicates the equivalent valence in electronic charge units assigned to the transition. F is the Faraday constant, Vm is voltage, R is the universal gas constant, and T is temperature in Kelvin.
Gagnon and Bezanilla, 2009.