TABLE I.

Rate constants for Scheme 1

Transition Channel 1 Channel 2 Channel 3 
 Rate constant Partial charge Rate constant Partial charge Rate constant Partial charge 
 s−1 e0 s−1 e0 s−1 e0 
kO,I1 86 0.39 32 0.53 31 0.57 
kI1,O 50,000 M−1 −0.11 48,000 M−1 −0.11 37,000 M−1 −0.03 
kI1,I2 450 0.45 410 0.47 1,100 0.29 
kI2,I1 570 −0.36 480 −0.30 530 −0.34 
Transition Channel 1 Channel 2 Channel 3 
 Rate constant Partial charge Rate constant Partial charge Rate constant Partial charge 
 s−1 e0 s−1 e0 s−1 e0 
kO,I1 86 0.39 32 0.53 31 0.57 
kI1,O 50,000 M−1 −0.11 48,000 M−1 −0.11 37,000 M−1 −0.03 
kI1,I2 450 0.45 410 0.47 1,100 0.29 
kI2,I1 570 −0.36 480 −0.30 530 −0.34 
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