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TABLE III

Exponential Components and States for Scheme 2 with the Indicated Rate Constants for kC2-C1.

kC2-C1 (s−1)
1
10
100
200
1,000
5,000
10,000
100,000
Components and states         
tC1 (ms) 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 
tC2 (ms) 1000 100 10 5 1 0.2 0.1 0.010 
τE1 (ms) 0.999 0.995 0.950 0.901 0.586 0.180 0.095 0.010 
τE2 (ms) 2001 201.0 21.05 11.10 3.414 2.220 2.105 2.010 
aE1 0.499 0.495 0.450 0.402 0.146 0.010 0.0025 0.00003 
aE2 0.501 0.505 0.550 0.598 0.854 0.990 0.9975 0.99997 
τ{C1} (ms) 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 
τ{C1C2} (ms) The τ of the decay of {C1C2} approaches that of E2 at longer times        
a{C1} 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 
a{C1C2} 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 
kC2-C1 (s−1)
1
10
100
200
1,000
5,000
10,000
100,000
Components and states         
tC1 (ms) 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 
tC2 (ms) 1000 100 10 5 1 0.2 0.1 0.010 
τE1 (ms) 0.999 0.995 0.950 0.901 0.586 0.180 0.095 0.010 
τE2 (ms) 2001 201.0 21.05 11.10 3.414 2.220 2.105 2.010 
aE1 0.499 0.495 0.450 0.402 0.146 0.010 0.0025 0.00003 
aE2 0.501 0.505 0.550 0.598 0.854 0.990 0.9975 0.99997 
τ{C1} (ms) 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 
τ{C1C2} (ms) The τ of the decay of {C1C2} approaches that of E2 at longer times        
a{C1} 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 
a{C1C2} 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 

The abbreviations designating the exponential components and states are defined in Table I.

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